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|Section2= |Section3= |Section4= |Section7= |Section8= }} Copper(I) oxide or cuprous oxide is the inorganic compound with the formula Cu2O. It is one of the principal oxides of copper. This red-coloured solid is a component of some antifouling paints. The compound can appear either yellow or red, depending on the size of the particles.〔N. N. Greenwood, A. Earnshaw, ''Chemistry of the Elements'', 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.〕 Copper(I) oxide is found as the reddish mineral cuprite. ==Preparation== Copper(I) oxide may be produced by several methods.〔H. Wayne Richardson "Copper Compounds'' in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. 〕 Most straightforwardly, it arises via the oxidation of copper metal: : 4 Cu + O2 → 2 Cu2O Additives such as water and acids affect the rate of this process as well as the further oxidation to copper(II) oxides. It is also produced commercially by reduction of copper(II) solutions with sulfur dioxide. Aqueous cuprous chloride solutions react with base to give the same material. In all cases, the color is highly sensitive to the procedural details. Formation of copper(I) oxide is the basis of the Fehling's test and Benedict's test for reducing sugars. These sugars reduce an alkaline solution of a copper(II) salt, giving a bright red precipitate of Cu2O. It forms on silver-plated copper parts exposed to moisture when the silver layer is porous or damaged. This kind of corrosion is known as red plague. Little evidence exists for cuprous hydroxide, which is expected to rapidly undergo dehydration. A similar situation applies to the hydroxides of gold(I) and silver(I). 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Copper(I) oxide」の詳細全文を読む スポンサード リンク
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